Acryl liquid function
Alleen voor professioneel gebruik.
Merk: Function gefabriceerd in Duitsland
Met de geur van watermeloen
Acryl liquid de beste die te koop is.
Waarom nog teveel betalen als het zonder label(merk) veel goedkoper kan.
Onze acryl liquid / acrylvloeistof wordt door vele Bekende merken gevoerd in Nederland en Europa.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
SECTION 1: Identification of the substance/mixture and of the company/ undertaking
1.1 Product identifier Product name
: J-2Liquid(W1) Product code : 1001226
1.2 Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
1.3 Details of the supplier of the safety data sheet
Maiwell
Hochheider Weg 75 26123 Oldenburg
+49 441 37948480
e-mail address of person responsible for this SDS
National contact
Maiwell
Hochheider Weg 75 26123 Oldenburg +49 441 37948480
: mai@maiwell.com
1.4 Emergency telephone number
National advisory body/Poison Center
Telephone number
Supplier
Telephone number Hours of operation
: 1-352-323-3500
: (+49) 441 37948480
: Monday through Friday 8:00 am to 5:00 pm (UTC +2) Excluding National holidays
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 2, H225 Skin Irrit. 2, H315 Skin Sens. 1, H317 STOT SE 3, H335
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Date of issue/Date of revision : 11/12/2018 Date of previous issue : No previous validation Version : 1 1/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 2: Hazards identification
Hazard pictograms :
Signal word Hazard statements
Precautionary statements
Prevention Response
Storage Disposal
Hazardous ingredients
Supplemental label elements
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
: Danger
: Highly flammable liquid and vapor. Causes skin irritation.
May cause an allergic skin reaction. May cause respiratory irritation.
: Wear protective gloves. Wear protective clothing. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
: Store locked up.
: Dispose of contents and container in accordance with all local, regional, national
and international regulations. : methyl methacrylate
: Not applicable.
: Not applicable.
Special packaging requirements
Containers to be fitted with child-resistant fastenings
Tactile warning of danger
2.3 Other hazards
3.2 Mixtures : Mixture
: Not applicable. : Not applicable.
: None known.
SECTION 3: Composition/information on ingredients
Other hazards which do not result in classification
Product/ingredient name
INCI Name
Identifiers
%
Classification
Regulation (EC) No. 1272/2008 [CLP]
Type
Date of issue/Date of revision : 11/12/2018 Date of previous issue : No previous validation Version : 1 2/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 3: Composition/information on ingredients
methyl methacrylate
N,N-dimethyl-p-toluidine
Methyl methacrylate
Dimethyltolylamine
EC: 201-297-1 CAS: 80-62-6 Index: 607-035-00-6
EC: 202-805-4 CAS: 99-97-8 Index: 612-056-00-9
≥90
<1
Flam. Liq. 2, H225 Skin Irrit. 2, H315 Skin Sens. 1, H317
STOT SE 3, H335
Acute Tox. 3, H301
Acute Tox. 3, H311
Acute Tox. 2, H330
STOT RE 2, H373 Aquatic Chronic 3, H412
[1] [2]
[1]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
Eye contact : Inhalation :
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Ingestion
:
:
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 3/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 4: First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact
Inhalation Skin contact Ingestion
: Adverse symptoms may include the following: pain or irritation
watering
redness
: No specific data. : No specific data. : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled. Specific treatments : No specific treatment.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO2, water spray (fog) or foam. media
Unsuitable extinguishing : Do not use water jet. media
5.2 Special hazards arising from the substance or mixture
Hazards from the substance or mixture
Hazardous combustion products
5.3 Advice for firefighters
Special protective actions for fire-fighters
Special protective equipment for fire-fighters
: Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.
: Decomposition products may include the following materials: carbon dioxide
carbon monoxide
: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 4/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
For emergency responders
6.2 Environmental precautions
: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
: If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
6.3 Methods and materials for containment and cleaning up
Small spill
Large spill
6.4 Reference to other sections
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product.
: See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures
: Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 5/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 7: Handling and storage
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities
Shield UV light sources. Do not store above the following temperature: 10°C (50°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Inhibitor requires oxygen to function. Maintain proper headspace and re-aerate the product by mixing every 3 months.
Seveso Directive - Reporting thresholds (in tonnes) Danger criteria
7.3 Specific end use(s)
Recommendations : Not available.
Industrial sector specific : Not available. solutions
SECTION 8: Exposure controls/personal protection
The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases.
Category
Notification and MAPP threshold
Safety report threshold
P5c
5000
50000
8.1 Control parameters
Occupational exposure limits
Recommended monitoring : procedures
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Product/ingredient name
Exposure limit values
methyl methacrylate
EU OEL (Europe, 12/2017). Notes: list of indicative occupational exposure limit values
TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes.
DNELs/DMELs
No DNELs/DMELs available.
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 6/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 8: Exposure controls/personal protection
PNECs
No PNECs available.
8.2 Exposure controls
Appropriate engineering : controls
Individual protection measures
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Hygiene measures
Eye/face protection
Skin protection
Hand protection
Body protection
Other skin protection Respiratory protection
Environmental exposure controls
: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods.
: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
: Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 7/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state :
Color :
Odor :
Odor threshold :
pH :
Melting point/freezing point :
Initial boiling point and : boiling range
Flash point :
Evaporation rate :
Flammability (solid, gas) :
Upper/lower flammability or : explosive limits
Vapor pressure :
Vapor density :
Relative density :
Solubility(ies) :
Partition coefficient: n-octanol/ : water
Auto-ignition temperature : Decomposition temperature : Viscosity : Explosive properties : Oxidizing properties :
9.2 Other information
Solubility in water :
Liquid.
Colorless to slight violet or Blue. [Light] Sweetish.
Not available.
Not available.
Not available.
100°C
Closed cup: -18 to 23°C >1 (butyl acetate = 1) Not available.
Lower: 1.7%
Upper: 8.2% Not available.
>1 [Air = 1] Not available. Not available. Not available.
421°C
Not available. Not available. Not available. Not available.
Not available.
SECTION 10: Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
10.5 Incompatible materials
: No specific test data related to reactivity available for this product or its ingredients.
: The product is stable.
: Hazardous polymerization may occur under certain conditions of storage or use. These could cause the product to polymerize exothermically. Unintentional contact with them should be avoided.
: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
: Reactive or incompatible with the following materials: oxidizing materials
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 8/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 10: Stability and reactivity
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products decomposition products should not be produced.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Conclusion/Summary
Acute toxicity estimates
Irritation/Corrosion
Conclusion/Summary
Sensitization
Conclusion/Summary
Mutagenicity
Conclusion/Summary
Carcinogenicity
Conclusion/Summary
Reproductive toxicity
Conclusion/Summary
Teratogenicity
: Not available. Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Not available.
Information on the likely : Not available.
routes of exposure
Date of issue/Date of revision : 11/12/2018 Date of previous issue : No previous validation Version : 1 9/15
Product/ingredient name
Result
Species
Dose
Exposure
methyl methacrylate N,N-dimethyl-p-toluidine
LC50 Inhalation Vapor LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor LD50 Oral
Rat Rabbit Rat Rat Rat
78000 mg/m3 >5 g/kg
7872 mg/kg 1400 mg/m3 980 mg/kg
4 hours -
-
4 hours -
: Not available.
: Not available.
: Not available.
: Not available.
: Not available.
: Not available.
Route
ATE value
Oral
Dermal
Inhalation (vapors)
10363.2 mg/kg 31089.5 mg/kg 145.1 mg/l
Conclusion/Summary
Product/ingredient name
Category
Route of exposure
Target organs
J-2 Liquid
methyl methacrylate
Category 3 Category 3
Not applicable. Not applicable.
Respiratory tract irritation Respiratory tract irritation
Product/ingredient name
Category
Route of exposure
Target organs
N,N-dimethyl-p-toluidine
Category 2
Not determined
Not determined
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 11: Toxicological information
Potential acute health effects
Eye contact : Inhalation : Skin contact : Ingestion :
No known significant effects or critical hazards.
May cause respiratory irritation.
Causes skin irritation. May cause an allergic skin reaction. No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact :
Inhalation : Skin contact : Ingestion :
Adverse symptoms may include the following: pain or irritation
watering
redness
No specific data. No specific data. No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure
Potential immediate effects
Potential delayed effects
Long term exposure
Potential immediate effects
Not available.
Conclusion/Summary General
Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects
12.1 Toxicity
Conclusion/Summary : Not available.
12.2 Persistence and degradability
Date of issue/Date of revision : 11/12/2018 Date of previous issue : No previous validation Version : 1 10/15
: Not available. : Not available.
: Not available.
: Not available. Potential chronic health effects
Potential delayed effects
: Not available.
: Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
: No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards.
: Not available. SECTION 12: Ecological information
Other information
Product/ingredient name
Result
Species
Exposure
methyl methacrylate N,N-dimethyl-p-toluidine
Acute LC50 130000 μg/l Fresh water Acute LC50 46000 μg/l Fresh water
Fish - Pimephales promelas - Adult
Fish - Pimephales promelas
96 hours 96 hours
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 12: Ecological information
Conclusion/Summary : 12.3 Bioaccumulative potential
12.4 Mobility in soil
Not available.
Product/ingredient name
LogPow
BCF
Potential
methyl methacrylate N,N-dimethyl-p-toluidine
1.38 1.729
- 33
low low
Soil/water partition : Not available. coefficient (KOC)
Mobility : Not available. 12.5 Results of PBT and vPvB assessment
PBT vPvB
: No known significant effects or critical hazards. SECTION 13: Disposal considerations
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
12.6 Other adverse effects
: Not applicable. : Not applicable.
Product
Methods of disposal
Hazardous waste
Packaging
Methods of disposal Special precautions
: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
: The classification of the product may meet the criteria for a hazardous waste.
: The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.
: This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 11/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 14: Transport information
ADR/RID
ADN
IMDG
IATA
14.1 UN number
UN1993
UN1993
UN1993
UN1993
14.2 UN proper shipping name
FLAMMABLE LIQUID, N.O.S. (methyl methacrylate)
FLAMMABLE LIQUID, N.O.S. (methyl methacrylate, N,N- Dimethyl-p-toluidine)
FLAMMABLE LIQUID, N.O.S. (methyl methacrylate)
FLAMMABLE LIQUID, N.O.S. (methyl methacrylate)
14.3 Transport hazard class(es)
3
3
3
3
14.4 Packing group
II
II
II
II
14.5 Environmental hazards
No.
No.
No.
No.
Additional information
ADR/RID ADN
14.6 Special precautions for user
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
: Specialprovisions640(C) Tunnel code (D/E)
: Specialprovisions640(C)
: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
: Not applicable.
Other EU regulations
Ozone depleting substances (1005/2009/EU)
Not listed.
Date of issue/Date of revision : 11/12/2018 Date of previous issue : No previous validation Version : 1 12/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 15: Regulatory information
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia Canada China Europe Japan
Malaysia
New Zealand Philippines Republic of Korea Taiwan
Thailand
Turkey
United States
Viet Nam
15.2 Chemical Safety Assessment
: Not determined.
: Not determined.
: Not determined.
: Not determined.
: Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined.
: Not determined. : Not determined. : Not determined. : Not determined. : Not determined. : Not determined. : Not determined. : Not determined. : Not determined.
: This product contains substances for which Chemical Safety Assessments are still required.
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 13/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 16: Other information
Indicates information that has changed from previously issued version.
Abbreviations and acronyms
: ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Full text of abbreviated H statements
Classification
Justification
Flam. Liq. 2, H225 Skin Irrit. 2, H315 Skin Sens. 1, H317 STOT SE 3, H335
Expert judgment Expert judgment Expert judgment Expert judgment
H225 H301 H311 H315 H317 H330 H335 H373
H412
Highly flammable liquid and vapor. Toxic if swallowed.
Toxic in contact with skin.
Causes skin irritation.
May cause an allergic skin reaction.
Fatal if inhaled.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]
Acute Tox. 2, H330 Acute Tox. 3, H301 Acute Tox. 3, H311 Aquatic Chronic 3, H412 Flam. Liq. 2, H225
Skin Irrit. 2, H315 Skin Sens. 1, H317 STOT RE 2, H373
STOT SE 3, H335
ACUTE TOXICITY (inhalation) - Category 2 ACUTE TOXICITY (oral) - Category 3
ACUTE TOXICITY (dermal) - Category 3 AQUATIC HAZARD (LONG-TERM) - Category 3 FLAMMABLE LIQUIDS - Category 2
SKIN CORROSION/IRRITATION - Category 2
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Date of printing
Date of issue/ Date of revision
Date of previous issue Version
Notice to reader
: 11/12/2018 : 11/12/2018
: No previous validation : 1
Date of issue/Date of revision
: 11/12/2018 Date of previous issue : No previous validation Version : 1 14/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830
J-2 Liquid
SECTION 16: Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Information contained within this SDS is only to be distributed as required by law.
Date of issue/Date of revision : 11/12/2018 Date of previous issue : No previous validation Version : 1 15/15